Reductive Coupling of Carbonyl Compounds to Pinacols with Samarium/Tmsci System

Mingxin Yu; Yongmin Zhang

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Reductive Coupling of Carbonyl Compounds to Pinacols with Samarium/Tmsci System

机译：Sa / Tmsci体系将羰基化合物还原成毒杀酚

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A number of systems have been developed for the preparation of pinacols from the reductive coupling of carbonyl compounds, e.g.magnesium, aqueous titanium trichloride in basic media,low valent cerium, samarium diiodide, and samarium diiodide-magnesium system.

机译：已经开发了许多系统，用于从羰基化合物例如镁，碱性介质中的三氯化钛水溶液，羰基化合物，低价铈，二碘化io和二碘化-镁体系的羰基化合物的还原偶联中制备匹纳克。

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《Organic Preparations and Procedures International: The New Journal for Organic Synthesis 》 |2001年第3期| 共4页
作者
Mingxin Yu; Yongmin Zhang;
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正文语种 eng
中图分类有机化学 ; 基本有机化学工业 ;
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专利

1. Reductive Coupling of Carbonyl Compounds to Pinacols with Samarium/Tmsci System [J] . Mingxin Yu, Yongmin Zhang Organic Preparations and Procedures International: The New Journal for Organic Synthesis . 2001 ,第2a3期

机译：Sa / Tmsci体系将羰基化合物还原成毒杀酚
2. Samarium mediated pinacol coupling of carbonyl compounds in the presence of a catalytic amount of iodine under aqueous media [J] . Wang Lei, Zhang Yong-Min Chinese Journal of Chemistry . 1999 ,第5期

机译：在水介质中催化量碘存在下，mar介导的羰基化合物的频哪醇偶联
3. Samarium Iodide-Catalyzed Pinacol Coupling of Carbonyl Compounds [J] . Ryoji Nomura, Tatsuya Matsuno, Takeshi Endo Journal of the American Chemical Society . 1996 ,第46期

机译：碘化mar催化羰基化合物的频哪醇偶联
4. Novel Catalytic System for One-Electron Reduction.Vanadium-Catalyzed Highly Diastereoselective Pinacol Coupling [C] . Toshikazu Hirao, Bunpei Hatano The Meeting of the Electrochemical Society . 2000

机译：一种用于单电子的新型催化系统。催化高度非致致映选择性皮卡糖耦合
5. Novel coupling reactions between Fisher carbene complexes and enyne-carbonyl compounds leading to complex polycyclic systems. [D] . Patti, Rajesh K. 2012

机译：Fisher卡宾配合物与烯炔羰基化合物之间的新型偶联反应可导致复杂的多环系统。
6. Intermolecular Metal-Catalyzed Reductive Coupling of Dienes Allenes and Enynes with Carbonyl Compounds and Imines [O] . Michael Holmes, Leyah A. Schwartz, Michael J. Krische -1

机译：分子间金属催化的二烯丙二烯和烯炔与羰基化合物和亚胺的还原偶联
7. A new approach to 3-hydroxyprolinol derivatives by samarium diiodide-mediated reductive coupling of chiral nitrone with carbonyl compounds [O] . Wu Shao-Feng, Zheng Xiao, Ruan Yuan-Ping, 2009

机译：二碘化sa介导的手性硝酮与羰基化合物的还原偶联制取3-羟基脯氨醇衍生物的新方法
8. Reductive Coupling of Carbonyl Compounds with Zinc and Trimethylchlorosilane to Produce O-Silylated Pinacols. Effect of Ultrasonic Waves [R] . So, J. H., Park, M. K., Boudjouk, P. 1988

机译：羰基化合物与锌和三甲基氯硅烷的还原偶联生成O-甲硅烷基化的频哪醇。超声波的影响

Reductive Coupling of Carbonyl Compounds to Pinacols with Samarium/Tmsci System

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