首页> 外文期刊>Russian journal of electrochemistry >Numerical modeling of a four-electrode electrochemical accelerometer based on natural convection: The Boussinesq flow model vs. the compressible flow model
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Numerical modeling of a four-electrode electrochemical accelerometer based on natural convection: The Boussinesq flow model vs. the compressible flow model

机译:基于自然对流的四电极电化学加速度计的数值建模:Boussinesq流动模型与可压缩流动模型

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摘要

Two-dimensional numerical simulations are conducted to study the feasibility of applying the Boussinesq approximation to the steady-state buoyancy-driven flow in a four-electrode electrochemical accelerometer. Two kinds of electrode layouts along the electrochemical cell, the anode-cathode-cathode-anode (ACCA) and the cathode-anode-anode-cathode (CAAC), are examined. The results from the model based on the Boussinesq approximation are compared to those from the compressible flow model. Though the Boussinesq flow model leads to fairly large quantitative deviations, it is capable of qualitatively estimating the output electric current when the output electric current increases linearly as the applied axial acceleration. A qualitative difference between the two models are found in the centerline density profiles in the electrochemical cell, which can be explained by the compressibility- induced acceleration/deceleration. It is found that the Boussinesq approximation is good enough for the estimation of the electric current at a single electrode while can make large deviations of the cathodic current difference, i.e., the output electric current in this study.
机译:进行了二维数值模拟,以研究将Boussinesq逼近应用于四电极电化学加速度计中的稳态浮力驱动流的可行性。考察了沿电化学电池的两种电极布局,即阳极-阴极-阴极-阳极(ACCA)和阴极-阳极-阳极-阴极(CAAC)。将基于Boussinesq逼近的模型结果与可压缩流模型的结果进行比较。尽管Boussinesq流动模型会导致相当大的定量偏差,但是当输出电流随着所施加的轴向加速度线性增加时,它能够定性地估计输出电流。在电化学电池的中心线密度分布图中发现了这两种模型之间的质量差异,这可以用可压缩性引起的加速/减速来解释。已经发现,在该研究中,Boussinesq逼近足以用于估计单个电极上的电流,同时可以使阴极电流差即输出电流有较大的偏差。

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