New Complex of Manganese(II) with Schiff Base Derived from Furaldehyde and Diethylenetriamine1

摘要

A new manganeses(II) complex MnLCl2·CH3OH (L = N,N'-bis(furaldehyde)diethylenetri-amine) was synthesized and characterized by X-ray crystallographic analysis. The crystals are orthorhombic, space group Pnma with cell parameters a = 20.998(6), b = 13.314(5), c = 6.785(8) A, Z= 4, R1 = 0.0609, and wR2 = 0.2116. The coordination geometry around Mn(II) atom is a trigonal-bipyramidic containing one tridenate ligand L and two Cl~- ions.