Synthesis and Crystal Structure of Isotrithionedithiolato-bis(phenanthroIine)zinc(II)

摘要

The synthesis of amixed-ligand complex l,3-dithiole-2-thione-4,5-dithiolato-bis(l,10-phenanthro-line)zinc(II),[Zn(Dmit)(Phen)2],is described.The crystals are monoclinic,space group P2_1,a=11.868(2)A,b=13.122(3)A,c=17.010(3)A,beta=102.01(3)°,Z=4.The coordination polyhedron of the Zn(II)atom is an octahedron formed by two sulfur atoms of the Dmit ligand and four nitrogen atoms of the two Phen ligands.The complex is studied by IR and UV spectroscopy.