Calculation of the Magnetic Properties of Low-Symmetry Polynuclear Complexes.Exchange Interactions in the Hexanuclear Chromium(III) Pivalate

摘要

A theory that allows numerical calculations and interpretation of magnetic properties of low-symmetry polynuclear complexes containing a large number of orbitally non-degenerate transition metal ions is developed by the irreducible tensor operator method.The potential of the theory was illustrated using the chro-mium(III) complex,Cr_6O_2(OH)_2[O_2CC(CH_3)_3]_(11) as an example.