OXIDATION OF OXIMES WITH CHROMIUM TRIOXIDE IN DIMETHYL SULPHOXIDE UNDER HOMOGENEOUS CONDITIONS

摘要

Oxidative cleavage of oximes to their parent aldehydes and ketones with chromium trioxide-dimethyl sulphoxide system at room temperature under homogeneous conditions in the yield between 82-92% is described. The main advantage of the present method is no need of preparation of hexavalent chromium-based reagent. The present procedure is an extension of our previous work.