In situ growth of carbon nanotubes in alumina-zirconia nanocomposite matrix prepared by solution combustion method

摘要

In this work successful synthesis of multiwall carbon nanotube (CNT) using solution combustion and chemical vapor deposition (CVD) methods are reported. Ceramic nanocomposite samples of (Al_(2-x)Fe_xO_3)-(y)ZrO_2 formula with x = 0.017, 0.034 and 0.17 and y = 0.15 were initially prepared. These were then subjected to CVD process during which the in situ reduction of iron oxide to metallic iron (Fe/Fe_3C) phase/s provided the necessary catalyst for the CNT formation. The formation of long flexible filaments with a smooth and regular surface bridging between alumina-zirconia (AZ) grains could be detected. The diameters of the formed filaments were in the range of ～70 to ～320 nm and length of the order of some tens of micrometers. However, transmission electron microscope (TEM) examinations also revealed the existence of small amounts of Bamboo-like carbon along with more or less straight CNTs. This could be related to the lack of strong interactions between the metallic iron phase/s and the nanocomposite support.