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A Dynamic Approach to the Sudden Jump Model in Single Molecule Spectroscopy

机译:单分子光谱中突然跳跃模型的动态方法

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Various theories that use the sudden jump model to explain the time dependence of the optical band of a single molecule in a fluctuating environment are analyzed. It is shown that the dynamic theory of the optical band, based on the Hamiltonian of the system, should necessarily include the initial conditions for the quantum system. We show how these initial conditions should be chosen for the dynamic theory to properly describe the quantum jumps of the optical band of a single molecule. Unlike stochastic theories based on the sudden jump model, the dynamic theory predicts several absorptances of a single molecule and directly connects the absorptance fluctuations with this fact. The theory is used to account for the time dependence of the broadening of experimentally measured lines of individual molecules.
机译:分析了使用突然跳跃模型来解释波动环境中单个分子的光学带的时间依赖性的各种理论。结果表明,基于系统的哈密顿量的光带动力学理论必须包含量子系统的初始条件。我们展示了如何为动力学理论选择这些初始条件,以正确描述单个分子的光学带的量子跃迁。与基于突然跳跃模型的随机理论不同,动力学理论预测单个分子的多个吸收率,并将吸收率波动直接与此事实联系起来。该理论用于解释单个分子的实验测量线拓宽的时间依赖性。

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