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Study of the Energy Level Structure of Ions of the Indium Isoelectronic Sequence

机译:铟等电子序列离子能级结构的研究

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The structure of an energy level system for 54 ions of the indium isoelectronic sequence is studied on the basis of the relativistic Dirac-Fock self-consistent field method with the configuration interaction taken into account. A special attention is paid to the determination of the ground states of the ions, which is a complicated problem, because the ground-state configuration and the lowest term change several times along the indium isoelectronic sequence: at the beginning of the sequence, the ground-state configuration is 5s~25p, it becomes 5s~24f and Pr~(10+), the ground-state configuration of the Sm~(13+) ion is 5s~24f, and, finally, it is 4f~3, beginning from the Eu~(14+) ion. On the basis of theoretical calculations, the ground-state ionization potentials are determined for each ion. The influence of interaction of the 5s~25d~2D_(3/2,5/2) configuration with the 5s5p~2 configuration on the ~2D_(3/2,5/2) levels of the latter was also studied.
机译:在相对论狄拉克-福克自洽场方法的基础上,考虑了构型相互作用,研究了铟等电子序列中54个离子的能级系统的结构。要特别注意确定离子的基态,这是一个复杂的问题,因为基态的构型和最低项沿铟等电子序列发生了数次变化:在序列的开头,基态构型为5s〜25p,变为5s〜24f和Pr〜(10 +),Sm〜(13+)离子的基态构型为5s〜24f,最后为4f〜3,从Eu〜(14+)离子开始。根据理论计算,确定每个离子的基态电离电势。还研究了5s〜25d〜2D_(3 / 2,5 / 2)构型与5s5p〜2构型相互作用对后者〜2D_(3 / 2,5 / 2)水平的影响。

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