首页> 外文期刊>Oil gas European Magazine: International Edition of Erdol Erdgas Kohle >Exploiting the Synergy between Fluid Catalytic Cracking and Visbreaking to Increase the High - Value Product Yields
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Exploiting the Synergy between Fluid Catalytic Cracking and Visbreaking to Increase the High - Value Product Yields

机译:利用流体催化裂化和裂变的协同作用提高高产率产品产量。

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An investigation was carried out to test the feasibility of processing a 360-510 deg C visbreaker fraction in the fluid catalytic cracking unit, in order to maximize high-value product yields. It was found that in a commercial visbreaker unit with a soaker, the viscosity of visbreaker residue (>200 deg C) and the conversion of the visbreaker feedstock - vacuum residue (>482 deg C)-correlated directly with vacuum residue viscosity. Depending on the conversion in the visbreaker, the yield of 360-150 dg C cut varied in the range 16-24% on feed. Characterization of this fraction showed no difference in quality with conversion and a high level of gasoline precursors -68%. Cracking experiments with a heavy vacuum gas oil, distilled from Russian Export Blend crude oil (73% gasoline precursors) and with an 80% Russian Export Blend heavy vacuum gas oil/20% visbreaker 360-510 deg C cut blend using a commercial equilibrium catalyst in a laboratory MAT unit exhibited almost the same yield patterns. Therefore, addition of 25% of the visbreaker 360-510 deg cut to the FCC feed does not negatively affect the FCC yield pattern. Deriving the 360-510 deg C fraction from the visbreaker and processing it in the FCC unit could increase the crude oil conversion by 2.8%. The yield of high value LPG and gasoline could increase by 0.8% and 2.6% of the crude oil respectively whilst reducing yields of fuel oil and FCC LCO by 3.7% and 0.6% respectively. Characterization of the 200-360 deg C visbreaker cut showed that this material is more suitable as a component for transportation diesel than FCC LCO because of the lower aromatics content, 41% versus 72% of FCC LCO and higher cetane index -42 versus 21 of FCC LCO.
机译:为了使高价值的产品收率最大化,进行了一项研究以测试在流化催化裂化装置中加工360-510℃减粘剂馏分的可行性。发现在具有浸透剂的商业减粘器单元中,减粘剂残余物的粘度(> 200℃)和减粘剂原料的转化率-真空残余物(> 482℃)与真空残余物粘度直接相关。根据减粘破碎机中的转化率,进料的360-150 dg C馏分的产率在16-24%的范围内变化。该馏分的表征显示,转化率和高水平的汽油前驱物-68%的质量没有差异。使用重油粗柴油进行裂化实验,该重油粗柴油是使用工业平衡催化剂从俄罗斯Export Blend原油(73%的汽油前体)中蒸馏出来的,以及80%Russian Export Blend重真空瓦斯油/ 20%减粘剂360-510℃的馏分混合物在实验室MAT单元中,其产量模式几乎相同。因此,将25%减粘剂360-510度减粘剂添加到FCC进料中不会对FCC产量产生负面影响。从减粘剂获得360-510℃馏分并在FCC装置中进行处理可以使原油转化率提高2.8%。高价值液化石油气和汽油的收率分别可以提高原油的0.8%和2.6%,而燃料油和FCC的LCO的收率则分别降低3.7%和0.6%。 200-360℃减粘剂馏分的特征表明,该材料比FCC LCO更适合用作运输柴油的组分,因为芳烃含量较低,FCC LCO为41%对72%,十六烷值较高-42对21为FCC LCO。

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