Immobilization of luminescent nanosilicon in a microfine polytetrafluoroethylene matrix by means of supercritical carbon dioxide

摘要

With the use of supercritical carbon dioxide (SC-CO2), the matrix immobilization of photoluminescent silicon nanocrystals (nc-Si) in polytetrafluoroethylene microparticles (mp-PTFE) is performed, which leads to the formation of mp-PTFEc-Si photoluminescent nanocomposite containing similar to 10(3)-10(4) nc-Si particles per mp-PTFE particle (1-2 mu m in size). This approach is based on the effect of polymer swelling in SC-CO2, efficient SC-CO2-assisted transport of nanoparticles into the internal free volume of the polymer, and contraction of the nanocomposite after the release of CO2, an effect that prevents the subsequent agglutination of nanoparticles. Particles of nc-Si photoluminescent in the visible spectrum were synthesized from silicon suboxide powder (SiO (x) , x a parts per thousand 1) heated at various temperatures within 25-950A degrees C and then etched in concentrated hydrofluoric acid. The hydrosilylation procedure was used to graft 1-octadecene molecules to the surface of nc-Si particles. As a result, the photoluminescence intensity of nc-Si increased substantially. According to TEM images and small angle X-ray scattering data, the maximum size of nc-Si particles did not exceed 5 nm and 7 nm, respectively, and the core of these nanoparticles consisted of crystalline silicon. The structure and spectral properties of the initial nc-Si particles and synthesized mp-PTFEc-Si photoluminescent nanocomposite microparticles were studied.