Three-Dimensional Simulation of Free-Radical Block Polymerization of Diallyl Isophthalate by the Monte Carlo Method

摘要

A model of the three-dimensional free-radical block polymerization of diallyl isophthalate to a limiting degree of conversion is developed. The core of the model is a reactor built on a cubic lattice of size 100 × 100 × 100. The influence of chain transfer to the monomer and of diffusion effect on the kinetic char-acteristics of the polymerization process is examined.