Dimethyll-Hydroxy-3,7-dimethyl-2,6-octadienylphosphonate.Development of Synthetic Procedures

摘要

With the goal of simulating phosphorylation of natural polyisoprenyl aldehydes which are promising low-molecular bioregulators [1-3],we examined reactions of citral (3,7-dimethyl-2,6-octadienal,a mixture of E and Z isomers) with trimethyl phosphite and dimethyl phosphonate in the presence of third-party reagents.