Synthesis of Acrylates and Methacrylates Based on tert-Butylperoxy-α-Chloroalkoxyethanes

摘要

Peroxide monomers are used as initiators of free radical processes and for the synthesis of modified copolymer having a complex of valuable properties [1]. The use of peroxide initiators with the (meth) acrylate fragments, α-located relative to peroxide group, is limited because of their lability, explosivity and spontaneous polymerization [1].