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Synthesis, characterization and fluorescence studies of novel bi-phenyl based acrylate and methacrylate

机译:新型联苯基丙烯酸酯和甲基丙烯酸酯的合成,表征和荧光研究

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摘要

4-[(1E)-3-(biphenyl-4-yl)buta-1,3-dien-1-yl]phenyl prop-2-enoate (ACH) and 4-[(1E)-3-(biphenyl-4-yl)buta-1,3-dien-1-yl]phenyl 2-methylprop-2-enoate (MCH) was synthesized from biphenyl in three steps and their structures were confirmed by elemental analysis, IR, NMR (~1H, ~(13)C, DEPT135, 1H-1H COSY, ~1H-~(13C) HSQC and ~1H-~(13)C HMBC) spectroscopic techniques. In this present study, various physicochemical characteristics we demonstrate solubility, color, absorbance and fluorescence property of novel biphenyl based acrylate and methacrylate measured in different solvents like benzene, dichloromethane, tetrahydrofuran, acetonitrile, dimethylsulfoxide and ethanol.
机译:丙-2-烯酸4-[((1E)-3-(联苯-4-基)丁-1,3-二烯-1-基]苯基(ACH)和4-[(1E)-3-(联苯-由联苯分三步合成了4-甲基)-2-甲基丙-2-烯丙基的1,3-二烯-1-基]苯基2-甲基丙-2-烯酸酯(MCH),并通过元素分析,IR,NMR(〜1H, 〜(13)C,DEPT135、1H-1H COSY,〜1H-〜(13C)HSQC和〜1H-〜(13)C HMBC)光谱技术。在本研究中,各种理化特性证明了在不同溶剂(如苯,二氯甲烷,四氢呋喃,乙腈,二甲基亚砜和乙醇)中测得的新型联苯丙烯酸酯和甲基丙烯酸酯的溶解度,颜色,吸光度和荧光性质。

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