Structural Features of Pseudooctahedral Molybdenum(VI) and Tungsten(VI) Oxomonoperoxo Complexes

V. S. Sergienko

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Structural Features of Pseudooctahedral Molybdenum(VI) and Tungsten(VI) Oxomonoperoxo Complexes

机译：伪八面体钼（VI）和钨（VI）氧过铜过氧化物配合物的结构特征

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The structural features of mono-, di-, and polynuclear (n > = 3) pseudooctahedral oxomonoperoxo-molybdenum(VI) and oxomonoperoxotungsten(VI) complexes (or pseudooctahedral MO_5(O_2) moieties incorporated in iso- and heteropolyperoxoanions), in particular, the geometry of a MO(O_2) moiety and the structural manifestations of the trans influence (SMTI) of the multiple-bonded peroxo ligand in comparison with the SMTI of the oxo ligand, have been surveyed.

机译：单，双和多核（n> = 3）伪八面体氧杂单过氧钼（VI）和氧杂单氧杂钨（VI）配合物（或掺入异-和杂多过氧阴离子的伪八面体MO_5（O_2）部分）的结构特征，考察了MO（O_2）部分的几何形状以及与氧代配体的SMTI相比，多重键合过氧代配体的反式影响（SMTI）的结构表现。

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《Russian Journal of Inorganic Chemistry》 |2004年第1期|共23页
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V. S. Sergienko;
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中图分类无机化学;
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Structural Features of Pseudooctahedral Molybdenum(VI) and Tungsten(VI) Oxomonoperoxo Complexes

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