Reaction of 3-(Ethylamino)-2,2-dimethylpropanal with Alkylene Phosphites

M. B. Gazizov; R. A. Khairullin; A. I. Alekhina

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Reaction of 3-(Ethylamino)-2,2-dimethylpropanal with Alkylene Phosphites

机译：3-（乙基氨基）-2,2-二甲基丙醛与亚磷酸亚烷基酯的反应

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It is known that dialkylphosphites react with 3-(mono-alkylamino)-substituted aldehydes to form 3-(alkyl-amino)-1-hydroxyphosphonates. Alkylene phosphites were not previously entered into this reaction. The aim of this work was to determine the structure of products of the reaction of alkylene phosphite I with 3-(ethylamino)-2,2-dimethylpropanal II and their subsequent acylation to obtain new polyfunctional organophosphorus compounds.

机译：已知亚磷酸二烷基酯与3-（单烷基氨基）-取代的醛反应形成3-（烷基-氨基）-1-羟基膦酸酯。亚磷酸亚烷基酯没有预先进入该反应。这项工作的目的是确定亚磷酸亚烷基酯I与3-（乙基氨基）-2,2-二甲基丙醛II的反应及其随后的酰化反应以获得新的多官能有机磷化合物的产物的结构。

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《Russian Journal of General Chemistry》 |2011年第7期|共2页
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M. B. Gazizov; R. A. Khairullin; A. I. Alekhina;
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1. Reaction of 3-(Ethylamino)-2,2-dimethylpropanal with Alkylene Phosphites [J] . M. B. Gazizov, R. A. Khairullin, A. I. Alekhina Russian Journal of General Chemistry . 2011,第7期

机译：3-（乙基氨基）-2,2-二甲基丙醛与亚磷酸亚烷基酯的反应
2. Reaction of 3-(Dimethylamino)-2,2-dimethylpropanal with Trialkylphosphites in the Presence of Acetic Anhydride [J] . M. B. Gazizov, R. A. Khairullin, A. I. Alekhina Russian Journal of General Chemistry . 2011,第7期

机译：乙酸酐存在下3-（二甲氨基）-2,2-二甲基丙醛与亚磷酸三烷基酯的反应
3. On the Surface-Catalyzed Reaction between the Gases 2,2-Dimethylpropanal and Methanamine.Formation of Active-Site Imines [J] . Linda M.Mascavage, Philip E.Sonnet, David R.Dalton The Journal of Organic Chemistry . 2006,第9期

机译：气体2,2-二甲基丙醛与甲胺之间的表面催化反应活性位亚胺的形成
4. Novel Convenient Method for the Resolution of 1, 1'-Binaphthalene-2,2'-Diol Via a Phosphite Using (-)-Menthol as Resolving Agent [C] . Journal of Tsinghua University: science and technology . 2001

机译：以（-）-薄荷醇为拆分剂通过亚磷酸酯拆分1，1'-萘-2,2'-二醇的简便方法
5. Synthesis of novel chiral phosphinite, phosphite and phosphinous amide ligands and their applications on the asymmetric catalytic reactions. [D] . Guo, Rongwei. 2002

机译：新型手性次膦酸酯，亚磷酸酯和次膦酰胺配体的合成及其在不对称催化反应中的应用。
6. Synthesis and Characterization of Polycarbonates by Melt Phase Interchange Reactions of Alkylene and Arylene Diacetates with Alkylene and Arylene Diphenyl Dicarbonates [O] . Bassam A. Sweileh, Yusuf M. Al-Hiari, Mohammad H. Kailani, 2010

机译：亚烷基和亚芳基二乙酸酯与亚芳基和亚芳基二苯基碳酸酯的熔融相变反应合成聚碳酸酯及其表征
7. Reaction of Grignard Reagents with Benzaldehyde, 2,2-Dimethylpropanal and Cinnamates of Chiral Alcohols in Chiral Solvents. [O] . Lars Jalander, Rolf Strandberg, Pentti Kuusela, 1983

机译：格氏试剂与苯甲醛，2,2-二甲基丙戊糖和手性溶剂的手性醇的反应。
8. Rearrangement of Closo-3,3-(PPh3)2-3-H-1-(R)-3,1,2-IrC2B9H10 to Closo-2,2-(PPh3)2-H-8-(R)-2,1,8-IrC2B9H10. Synthesis and X-Ray Structure of Closo-2,2-(PPh3)2-2-H-8-(C6H5)-2,1,8-IrC2B9H10. [R] . Doi, J. A., Mizusawa, E. A., Knobler, C. B., 1983

机译：Closo-3,3-（pph3）2-3-H-1-（R）-3,1,2-IrC2B9H10重排为Closo-2,2-（pph3）2-H-8-（R） - 2,1,8-IrC2B9H10。 Closo-2,2-（pph 3）2-2-H-8-（C 6 H 5）-2,1,8-IrC 2 B 9 H 10的合成和X射线结构。

Reaction of 3-(Ethylamino)-2,2-dimethylpropanal with Alkylene Phosphites

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