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Comparison of Solvation Ability and Viscosity Effects of Solvents on Diels-Alder Reaction

机译:溶剂对Diels-Alder反应的溶剂化能力和粘度效应的比较

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摘要

The suggested in publications dependence of the Diels-Alder reaction parameters on the viscosity of the environment is discussed. The preferred description is shown to base on the principle of the linearity of the free energies. In the majority of cases a crucial factor is the capability of solvents of electrophilic solvation.
机译:讨论了出版物中建议的Diels-Alder反应参数对环境粘度的依赖性。示出的优选描述是基于自由能的线性原理。在大多数情况下,关键因素是亲电溶剂的能力。

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