Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex

V.V.Potekhin; S.N.Soloveva; V.M.Potekhin

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Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex

机译：在四水合钯（II）存在下，氧对铁（II）水合物的催化氧化作用

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The catalytic oxidation of iron(II) with oxygen occurs along with an autocatalytic reaction between palladium(II) tetraaqua complex and iron(II) aqua complex in an oxygen atmosphere.The reaction is catalyzed by a compound of palladium in an intermediate oxidation state,presumably by a small palladium cluster formed in the course of the reduction of palladium(II) tetraaqua complex with iron(II) aqua complex.

机译：在氧气气氛中，四水合钯（II）与水合铁（II）之间发生自催化反应，同时发生氧对铁（II）的催化氧化反应，该反应由处于中间氧化态的钯化合物进行催化，大概是由钯（II）四水配合物与铁（II）水配合物还原过程中形成的小的钯簇形成的。

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《Russian Journal of General Chemistry》 |2004年第5期|共4页
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V.V.Potekhin; S.N.Soloveva; V.M.Potekhin;
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机译：在四水合钯（II）存在下，氧对铁（II）水合物的催化氧化作用
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Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex

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