Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols

N.M.Khvoinova; D.V.Muslin; S.Ya.Khorshev

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Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols

机译：羧酸和三氟乙酸的混合酸酐作为酰化剂：I. 3,5-二叔丁基苯甲酰基三氟乙酸酯与叔丁基苯酚的反应

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The rate and pathway of reactions of 3,5-di-tert-butylbenzoyl trifluoroacetate with tert-butyl-phenols depend on the number and position of bulky substituents determining the extent of steric shielding of the phenolic hydroxyl.

机译：3，5-二叔丁基苯甲酰基三氟乙酸酯与叔丁基苯酚的反应速率和反应路径取决于大取代基的数量和位置，从而决定了酚羟基的空间屏蔽程度。

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《Russian Journal of General Chemistry》 |2001年第11期|共3页
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N.M.Khvoinova; D.V.Muslin; S.Ya.Khorshev;
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1. Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols [J] . N.M.Khvoinova, D.V.Muslin, S.Ya.Khorshev Russian Journal of General Chemistry . 2001,第11期

机译：羧酸和三氟乙酸的混合酸酐作为酰化剂：I. 3,5-二叔丁基苯甲酰基三氟乙酸酯与叔丁基苯酚的反应
2. Acylation of aromatic ethers using different carboxylic acid anhydrides as acylating agents in the presence of nontoxic, noncorrosive resin amberlyst 15 as a solid acid catalyst [J] . Pande M.A., Samant S.D. Synthetic Communications . 2011,第4a6期

机译：在无毒，无腐蚀性树脂琥珀色粉15作为固体酸催化剂的情况下，使用不同的羧酸酐作为酰化剂对芳香族醚进行酰化
3. Lewis acid-catalyzed Friedel-Crafts acylation reaction using carboxylic acids as acylating agents [J] . Masato Kawamura, Dong Mei Cui, Teruyuki Hayashi, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003,第42期

机译：用羧酸作为酰化剂的路易斯酸催化的Friedel-Crafts酰化反应
4. THE NEW REARRANGEMENT OF N-ACYLATED 2- HYDROXYMETHYL-2-AMINO ACIDS TO 4,5- DIHYDRO-1,3-OXAZOLE-4-CARBOXYLIC ACIDS [C] . Janina E. Kaminska, Sebastian Olczyk, Beata Kolesinska the European Peptide Symposium . 2007

机译：N-酰化的2-羟甲基-2-氨基酸的新重排至4,5-二氢-1,3-氧唑-4-羧酸
5. Enthalpy and Entropy in Chemical Reactivity: I. Temperature Dependence of Secondary Deuterium Isotope Effects on the Acidity of Carboxylic Acids and Phenols, and a Rejection of any Inductive Contribution II. Kinetic and Mechanistic Studies of Reactions of Malonic Anhydrides III. Developing an ITC Method to Measure Heats of Proton Transfer [D] . Flach, Agnes 2012

机译：化学反应的焓和熵：I.次级氘同位素的温度依赖性对羧酸和苯酚酸度的影响，以及任何感应贡献的抑制II。丙二酸酐反应的动力学和机理研究。开发用于测量质子传递热的ITC方法
6. On The Two Component Microwave Mediated Reaction of Isonitriles with Carboxylic Acids: Regarding Alleged Formimidate Carboxylate Mixed Anhydrides [O] . Xuechen Li, Yu Yuan, William F. Berkowitz, -1

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7. Reaction of Sulfoxides with Acylating Reagents. IV. The Catalytic Effect of Both the Brönsted and Lewis Acids in the Oxygen Exchange Reaction of Diaryl Sulfoxides with Acetic Anhydride [O] . Masahiro Kise, Shigeru Oae 1970

机译：亚砜与酰化试剂的反应。 IV。 Brönsted和Lewis酸在乙酰磺酰胺氧交换反应中的Brönsted和路易斯酸的催化作用
8. ATTEMPTS TO PREPARE TRIFLUOROACETIC ACID BY THE REACTION OF COBALTIC FLUORIDES WITH ACETIC ANHYDRIDE AND ACETONITRILE [R] . 1945

机译：用乙酸酐和乙腈反应生成含氟乙酸制备三氟乙酸的试验

Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols

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