Reaction of Platinum Fulleride C_(60)Pt with Dihydroanthracene

摘要

9,10-Dihydroanthracene (C_(14)H_(12)) reacts with platinum fulleride C_(60)Pt at 513-623 K under anaerobic conditions to form anthracene and hydrofullerenes identified by IR and mass spectroscopy. The Pt 4f_(7/2) binding energy of platinum in the initial fulleride (72.4 eV) indicates partial charge transfer form Pt to C_(60) which agrees with the results of X-ray fluorescence spectroscopic study of C_(60)Pt.