Thermal Stability of Mono- and Polycyclic Petroxyalcohols and Their Derivatives by Thermal Analysis

摘要

A comparative study of the thermal stability of 33 mono- and polycyclic peroxyalcohols, as well as ethers and esters derived from them was performed by thermal analysis. Reaction orders and apparent rate constants of the first stage of peroxide decomposition were determined from the DTA curves. Semiempirical quantum-chemical calculations of the strength of the O-O bond in peroxycycloalkanols and peroxyalcohols of the adamantane series and their derived esters were performed.