Crystal Solvates of Porphyrins and Metalloporphyrins

摘要

The published data on the crystal solvates with nonpolar aromatic and electron-donor compounds obtained using different research methods as well as our own experimental results obtained by thermo-gravimetric analysis of the porphyrins and metalloporphyrins of natural and synthetic origin are generalized. The influence of the molecular structure of the porphyrins and metalloporphyrins on the composition, structural parameters, thermal and energy stability of crystal solvates formed through specific σ-and π-complexes with molecular ligands are considered.