Kinetics of Thermal Decomposition of Polyfunctional Substituted Azido-l,2,4-triazoles

摘要

The structural and kinetics regularities and the mechanism of the limiting step of thermal decomposition of the polyfunctional substituted 1,2,4-triazoles in the melt and in solutions of inert solvents were established. The activation parameters of the limiting step were determined. Polyfunctional substituents are found to show little effect on the rate of thermal decomposition of azide group in the azole ring.