Formal Kinetics of Reactions in Systems Acid Chloride (Anhydride)-Alcohol, Involving Hydrogen-bonded Complexes

摘要

A kinetic model of reactions in systems acid chloride (anhydride) alcohol, involving hydrogen-bonded complexes of various types, was constructed. The steps of their formation were included in the kinetic scheme. The dependence of the rate constants on the initial concentrations of the reactants in solvents (CCl4, n-hexane) was revealed. This dependence is caused by the fact that the activation energies of the reactions are close to the energies of hydrogen bonds formed in the systems.