New Approach to the Determination of the Equilibrium Radius of Intermolecular Interactions(Onsager Molecular Radius)in Solutions of Polar Compounds

摘要

At present a great deal of effort has been devoted to theoretical and experimental substantiation of the continual approach(approximation)in the statistical theory of liquids and the physics of liquid dielectrics.The principal goals have been to clarify the physical meaning of the equilibrium radius of intermolecular interactions(zeta_0)and Onsager molecular radius(a)in the liquid phase,as general structural energetic parameters of multiparticle interactions in liquids and solutions,as well as to establish interrelationship of these parameters.