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首页> 外文期刊>Russian Journal of General Chemistry >Kinetics of Phenol Oxidation with Iron-Manganese Concretions
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Kinetics of Phenol Oxidation with Iron-Manganese Concretions

机译:铁锰缩合反应氧化苯酚的动力学

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摘要

Kinetics of oxidation of phenols on the iron-manganese concretions in the temperature range 293-353 K at pH 5.5±0.5 was studied. Reaction of oxidation on the iron-manganese concretions has the second order by phenol. It is characterized by low activation energy, 17.5 kJ mol~(-1), due to the catalytic action of iron(III) oxide. Lower rate of oxidation of phenols on the iron-manganese concretions is observed as compared to oxidation on the pyrolusite surface. It occurs because of the decrease in MnO2 concentration in the iron-manganese concretions.
机译:研究了在pH 5.5±0.5的293-353 K温度范围内苯酚在铁锰固结体上的氧化动力学。铁-锰固结物上的氧化反应是苯酚的二级反应。由于氧化铁(III)的催化作用,其活化能低,为17.5 kJ mol〜(-1)。与在软锰矿表面上的氧化相比,观察到铁-锰固结体上苯酚的氧化速率较低。发生这种现象的原因是铁锰混凝土中MnO2浓度降低。

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