Chemistry of N,N-bis(silyloxy)enamines 7.Quaternization of tertiary amines and nitrogen-containing heterocycles by N,N-bis(silyloxy)enamines

摘要

Coupling of N,N-bis(silyloxy)enamines with tertiary amines and nitrogen-containing heterocycles affording the corresponding functionalized ammonium or iminium salts was studied.The area of its application was determined,and optimal procedures for the synthesis of the target products were proposed.The mechanism including the formation of conjugated nitroso alkene or a silylnitrosonium cation as key intermediates is discussed.