Aminomethylation of 4,4-bis(chloromethyl)oxazolidin-2-one and 4,4-bis(acetoxymethyl)oxazolidin-2-one

Korepin A. G.; Glushakova N. M.; Malygina V. S.; Kosilko V. P.; Barinova L. S.; Lagodzinskaya G. V.; Lodygina V. P.

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Aminomethylation of 4,4-bis(chloromethyl)oxazolidin-2-one and 4,4-bis(acetoxymethyl)oxazolidin-2-one

机译：4,4-双（氯甲基）恶唑烷-2-酮和4,4-双（乙酰氧基甲基）恶唑烷-2-酮的氨基甲基化

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N-Aminomethylation of 4,4-bis(chloromethyl)oxazolidin-2-one with formaldehyde and secondary amines is accompanied by the intramolecular ring closure to give 7a-chloromethyl3-oxohexahydroimidazo[1,5-c]oxazol-6-ium chlorides. In the case of the closely related 4,4-bis(acetoxymethyl)oxazolidin-2-one, only N-aminomethylation occurs.

机译：4,4-双（氯甲基）恶唑烷-2-酮与甲醛和仲胺的N-氨基甲基化伴随分子内环的闭合，得到7a-氯甲基3-氧六氢咪唑并[1,5-c]恶唑-6-鎓氯化物。在密切相关的4，4-双（乙酰氧基甲基）恶唑烷丁-2-酮的情况下，仅发生N-氨基甲基化。

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来源
《Russian Chemical Bulletin》 |2015年第1期|共5页
作者
Korepin A. G.; Glushakova N. M.; Malygina V. S.; Kosilko V. P.; Barinova L. S.; Lagodzinskaya G. V.; Lodygina V. P.;
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正文语种 eng
中图分类化学;
关键词
heterocyclic NH acids; aminomethylation; quaternary ammonium salts; chemical transformations of the salts;

机译：杂环NH酸;氨基甲基化;季铵盐;盐的化学转化;

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1. Aminomethylation of 4,4-bis(chloromethyl)oxazolidin-2-one and 4,4-bis(acetoxymethyl)oxazolidin-2-one [J] . Korepin A. G., Glushakova N. M., Malygina V. S., Russian Chemical Bulletin . 2015,第1期

机译：4,4-双（氯甲基）恶唑烷-2-酮和4,4-双（乙酰氧基甲基）恶唑烷-2-酮的氨基甲基化
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Aminomethylation of 4,4-bis(chloromethyl)oxazolidin-2-one and 4,4-bis(acetoxymethyl)oxazolidin-2-one

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