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Removal of disperse violet 28 from water using self-assembled organo-layered double hydroxides through a one-step process

机译:通过一步法使用自组装的有机层双氢氧化物从水中去除分散的紫罗兰色28

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摘要

A simple, one-step process including the self-assembly of organo-layered double hydroxides and removal of disperse dye simultaneously has been proposed. This one-step process can hopefully be applied for dye effluents removal due to its low operation cost and simplified process compared with a traditional organo-layered double hydroxides process. Here, the self-assembly of organo-layered double hydroxides was realized by adding both raw layered double hydroxides and the anionic surfactant sodium dodecylsulfate into wastewater, and then the one-step process was applied to remove disperse violet 28 from dyeing wastewater. The results showed a higher removal efficiency of disperse violet 28 in this one-step process than in a traditional organo-layered double hydroxide process because cooperative removal and synergism between the surfactant and disperse violet 28 in solution occurred to a large extent. The adsorption isotherm data could be described by the linear model, indicating a partitioning adsorption process. The adsorption kinetics was found to be well presented by the pseudo-second-order model, and the high activation energy (56.64 kJ mol(-1)) indicated that the adsorption was mainly a chemical process.
机译:已经提出了一种简单的一步法,包括有机层双氢氧化物的自组装和同时除去分散染料。与传统的有机层双氢氧化物工艺相比,这一步工艺有望降低染料成本,因为它的运行成本低且工艺简化。在此,通过将生的层状双氢氧化物和阴离子表面活性剂十二烷基硫酸钠一起加入废水中来实现有机层状双氢氧化物的自组装,然后应用一步法从染色废水中去除分散的紫罗兰28。结果表明,与传统的有机层双氢氧化物工艺相比,该一步法中分散紫罗兰28的去除效率更高,这是因为表面活性剂与溶液中分散紫罗兰28之间的协同去除和增效作用很大。吸附等温线数据可以用线性模型描述,表明分配吸附过程。假二阶模型显示了很好的吸附动力学,高活化能(56.64 kJ mol(-1))表明吸附主要是化学过程。

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