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Fabrication of titanium dioxide with durable superhydrophilicity by anodization

机译:通过阳极氧化制备具有持久超亲水性的二氧化钛

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摘要

Titanium-based materials with specific wettability show promising potential applications. In this paper, a titanium plate with hydrophilicity was simply synthesized by anodization with an electrolyte composed of NaOH, and their durability of wettability in the air was evaluated. The properties of the anodized Ti plate were characterized by a series of tests including FESEM, roughness, BET surface area, XRD, XPS, water contact angle, UV-vis absorption, photoluminescence, photocatalytic decomposition ability of methylene blue, self-cleaning property and durability of wettability in the air. When the processing time of the anodization was 10 minutes, the resulting titanium plate had a water contact angle of 0 degrees, which proved that it was superhydrophilic, and it possessed a micro-nano composite architecture with a distinct nanofiber network chemically constituted of anatase and sodium titanate. It also exhibited excellent photocatalytic properties under UV illumination, including high photocatalytic activity and photocatalytic decomposition ability, as well as good self-cleaning properties, all of which rendered it to have good durability of wettability. Significantly, it can maintain the superhydrophilicity for 6 months in air. It is proposed that it is a synergy effect originating from the topology, chemical constitution and excellent photocatalytic properties that leads to the durable superhydrophilicity.
机译:具有特定润湿性的钛基材料具有广阔的应用前景。在本文中,使用NaOH组成的电解质通过阳极氧化简单地合成了具有亲水性的钛板,并评估了其在空气中的可湿性。通过FESEM,粗糙度,BET表面积,XRD,XPS,水接触角,紫外可见吸收,光致发光,亚甲基蓝的光催化分解能力,自清洁性能和空气中可湿性的持久性。当阳极氧化处理时间为10分钟时,所得的钛板的水接触角为0度,证明其具有超亲水性,并且具有微纳米复合结构,具有由锐钛矿和钛酸钠。它还在紫外线照射下表现出优异的光催化性能,包括高的光催化活性和光催化分解能力,以及良好的自清洁性能,所有这些都使其具有良好的润湿性耐久性。值得注意的是,它可以在空气中维持6个月的超亲水性。提出的是源自拓扑,化学组成和优异的光催化性能的协同效应,从而导致持久的超亲水性。

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