Solution-phase photochemical transformation of 2-aroylbenzofurans: addition-elimination mechanism

Jindal Pooja; Sharma Geeta; Arora Rita; Kamboj Ramesh C.

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Solution-phase photochemical transformation of 2-aroylbenzofurans: addition-elimination mechanism

机译：2-芳基苯并呋喃的溶液相光化学转化：加成消除机理

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An efficient conversion of 2-aroylbenzofurans into arylbenzofurylmethanols through photoreduction has been described. In these molecules, the photo transformation occurred through the initial addition of solvent followed by elimination involving gamma-hydrogen abstraction. The photoproduct distribution markedly depends upon the substituent present on the benzofuran moiety.

机译：已经描述了通过光还原将2-芳基苯并呋喃有效转化为芳基苯并呋喃甲醇。在这些分子中，光转化是通过最初添加溶剂，然后通过消除涉及伽马-氢提取的溶剂而发生的。光产物的分布明显取决于苯并呋喃部分上存在的取代基。

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《Research on Chemical Intermediates》 |2015年第7期|共12页
作者
Jindal Pooja; Sharma Geeta; Arora Rita; Kamboj Ramesh C.;
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正文语种 eng
中图分类有机化学;
关键词
2-Aroylbenzofurans; Photoreduction; gamma-Hydrogen abstraction; Addition-elimination;

机译：2-芳基苯并呋喃;光还原;γ-氢提取;加成消除;

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Solution-phase photochemical transformation of 2-aroylbenzofurans: addition-elimination mechanism

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