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In Situ Remediation of 1, 4-Dioxane Using Electrical Resistance Heating

机译:电阻加热原位修复1,4-二恶烷

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摘要

Recent regulatory changes need more challenging treatment goals for 1, 4-dioxane. However, significant treatment limitations exist in part due to the high solubility and low Henry's law constant of 1, 4-dioxane. Two case studies are reported with substantial 1, 4-dioxane concentration reductions through in situ thermal remediation via electrical resistance heating (ERH). Concentration reductions greater than 99.8 percent of 1, 4-dioxane have been observed in the field using ERH. Concentrations of 1, 4-dioxane in air and steam extracted by an ERH vapor recovery system have also been evaluated. Laboratory studies were conducted to further understand the mechanisms that enable ERH remediation of 1, 4-dioxane. Vapor liquid equilibrium studies in water and soil were conducted and utilized to develop an ERH treatment cost model for 1, 4-dioxane. Existing field data were correlated to the 1, 4-dioxane treatment cost model. Field observations and laboratory testing indicate steam stripping that occurs through ERH remediation is an effective treatment method for 1, 4-dioxane.
机译:最近的法规变化需要针对1,4-二恶烷的更具挑战性的治疗目标。然而,由于1,4-二恶烷的高溶解度和低亨利定律常数,部分存在明显的治疗局限性。据报道,有两个案例研究表明,通过电阻加热(ERH)进行原位热修复,可显着降低1,4-二恶烷的浓度。在现场使用ERH观察到1,4-二恶烷的浓度降低大于99.8%。还评估了通过ERH蒸气回收系统提取的空气和蒸汽中1,4-二恶烷的浓度。进行了实验室研究,以进一步了解使ERH修复1,4-二恶烷的机理。进行了水和土壤中的蒸气液体平衡研究,并将其用于开发1,4-二恶烷的ERH处理成本模型。现有的现场数据与1,4-二恶烷处理成本模型相关。现场观察和实验室测试表明,通过ERH修复发生的汽提是一种有效的1,4-二恶烷处理方法。

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