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The Fluid Evolution Related to Talc Mineralization in the Hwanggangri Area, South Korea

机译:韩国黄冈里地区滑石成矿相关的流体演化

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Scores of talc deposits distributed in the Hwanggangri Mineralized Zone, South Korea are interpreted to have resulted from the contact metamorphic process related to the igneous intrusion of the Muamsa Granite. Talc usually occurs as an alteration product from tremolite, which is crystallized during the prograde stage. It commonly forms fine-grained, fibrous aggregates, or pseudomorphs after tremolite, and abundant tremolite is included as impurities in the talc ore. Quantitative X-ray diffraction analysis has shown that the ores can be divided into three types depending on the concentrations of talc; tale-tremolite ore (talc > 50 percent), tremolite-tale ore (10 percent < talc < 50 percent), and tremolite (talc < 10 percent) ores. Oxygen isotope compositions of those talc ores become higher from 10.9 approx 12.1 through 11.6 approx 12.3 to 11.9 approx 13.2 per thousand with increasing tremolite concentrations, while hydrogen isotope compositions are not so variable, -73 to -69 per thousand. The high value of the calculated delta~(18)O_(H_2O) of the fluids equilibrated with the tremolite may have resulted from the mixing of magmatic water with ~(18)O-enriched CO_2 evolved from the decarbonation reaction during the prograde stage. However, as the decarbonation reaction ceased during the retrograde stage, the inferred oxygen isotope compositions of talc-forming fluids show similar values to those of the igneous fluids.
机译:据推测,在韩国的黄冈里矿化区分布的滑石矿床有数十个,是由于与Muamsa花岗岩火成岩侵入有关的接触变质作用所致。滑石粉通常是透闪石的变质产物,在推进阶段会结晶。它通常在透闪石后形成细颗粒的纤维状聚集体或假晶形,并且大量的透闪石作为杂质包含在滑石矿石中。 X射线衍射定量分析表明,根据滑石粉的浓度,矿石可分为三种类型。透闪石矿石(滑石粉> 50%),透闪石矿石(10%<滑石粉<50%)和透闪石(滑石粉<10%)。随着透闪石浓度的增加,这些滑石的氧同位素组成从10.9约12.1增加到11.6约12.3到11.9约13.2 /千,而氢同位素组成变化不大,从-73到-69千。经透闪石平衡的流体计算出的δ〜(18)O_(H_2O)的高值可能是由于岩浆水与前阶段脱碳反应生成的〜(18)O富集的CO_2混合所致。然而,由于在逆行阶段脱碳反应停止,滑石形成流体的推断氧同位素组成显示出与火成流体相似的值。

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