Syngenetic inclusions of yimengite in diamond from Sese kimberlite (Zimbabwe)-evidence for metasomatic conditions of growth

摘要

Syngenetic inclusions of yimengite K (Cr,Ti,Mg,Fe,Al)_(12)O_(19),a potassium member of the magnetoplumbite mineral group,have been recorded in an octahedral macrodiamond from the Sese kimberlite (50 km south of Masvingo,Zimbabwe).One yimengite inclusion carries lamellae of chromite suggesting peridotitic diamond paragenesis.The diamond and inclusions were studied in situ in a plate polished parallel to (011).Cathodoluminescence (CL) imaging has shown blue colour and octahedral zonation of the diamond,lack of cracks and the location of five yimengites in different growth zones.Nitrogen (N) contents (at.ppm) in the diamond determined by Fourier transform infrared spectroscopy (FTIR) steadily decrease from 576 (core) to 146 (rim).N aggregation (%laB) is correspondingly 40% in the core and 30% in the rim.Hydrogen (H) content is high in the core,moderate in the intermediate and very high in the rim zones.Four yimengites were dated using the laser ~(40)Ar/~(39)Ar method.Three inclusions yielded total gas ages that agree with,or are younger than,or within error of,the Sese kimberlite eruption age (538+-11 Ma) but may be compromised by gas loss.One inclusion,with the highest tapped interface gas yield,gave a total gas age of 892+-21 Ma that is a likely minimum yimengite age.Time-TdegC constraints from N aggregation systematics give a range of possible ages from kimberlite eruption date back to Archean and do not resolve the variable results of the ~(40)Ar/~(39)Ar dating.Compared with the published chemistry of yimengite from kimberlites,inclusions from the Sese diamond contain higher Al,Mg,and Sr and have lower concentration of Fe~(3+).The chondrite-normalised REE pattern of the yimengite shows enrichment in LREE and depletion in HREE,but LREE/HREE fractionations are lower than for lindsleyite-mathiasite series mantle titanates and rather similar to the REE concentrations in kimeberlite and lamproite rocks.It is suggested that sese yimengite formed in the lithospheric mantle from metasomatism of chrome spinel by a fluid rich in Ti,K,Ba and LREE.