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首页> 外文期刊>Reaction kinetics,mechanisms and catalysis >Influence of the preparation method on the performance of CeO2-MoO3 catalyst for the selective catalytic reduction of NO with NH3
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Influence of the preparation method on the performance of CeO2-MoO3 catalyst for the selective catalytic reduction of NO with NH3

机译:制备方法对CeO2-MoO3催化剂对NH3选择性催化还原NO的性能的影响

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摘要

CeO2-MoO3 catalysts were prepared by three methods: single step sol-gel, homogeneous precipitation, hydrothermal. These catalysts were used for the selective catalytic reduction of NO with NH3 in the temperature range from 150 to 400 °C. The tested results suggested that the catalyst prepared by the hydrothermal method showed the higher NO conversion. The BET, XRD, H2-TPR, NH3-TPD and in situ DRIFTS characterization results indicated that the larger surface area, highly dispersed nanoctrystalline ceria, good redox ability and the stronger adsorption capacity for the NH3 should be the key factors to acquire the better NH3-SCR performance.
机译:CeO2-MoO3催化剂通过三种方法制备:单步溶胶-凝胶法,均相沉淀法,水热法。这些催化剂用于在150至400°C的温度范围内用NH3选择性催化还原NO。试验结果表明,水热法制备的催化剂具有较高的NO转化率。 BET,XRD,H2-TPR,NH3-TPD和原位DRIFTS表征结果表明,较大的表面积,高度分散的纳米晶二氧化铈,良好的氧化还原能力和对NH3的较强吸附能力应是获得更好吸附性能的关键因素。 NH3-SCR性能。

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