DIRECT KINETIC STUDY OF THE REACTION OF OH RADICALS WITH METHYL-ETHYL-KETONE

Emese Szabo; Gabor L. Zugner; Istvan Szilagyi

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DIRECT KINETIC STUDY OF THE REACTION OF OH RADICALS WITH METHYL-ETHYL-KETONE

机译：OH自由基与甲基-乙基-酮反应的直接动力学研究

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The low-pressure discharge flow technique with resonance fluorescence monitoring of OH has been applied to study the kinetics of the overall reaction: OH + CH3C(O)CH2CH3 → products (1) The rate constant of k1 = (1.09 ± 0.09(1 σ)) x 10~(-12) cm~3 molecule~(-1) s~(-1) has been determined at T = 297 ± 3 K. This value agrees well with the IUPAC recommendation which is based on photolysis kinetic studies.

机译：低压放电流技术和OH共振荧光监测技术已用于研究整个反应的动力学：OH + CH3C（O）CH2CH3→产物（1）k1的速率常数=（1.09±0.09（1σ）））x 10〜（-12）cm〜3分子〜（-1）s〜（-1）已确定为T = 297±3 K.该值与基于光解动力学研究的IUPAC建议非常吻合。

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《Reaction kinetics & catalysis letters》 |2008年第2期|共7页
作者
Emese Szabo; Gabor L. Zugner; Istvan Szilagyi;
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原文格式 PDF
正文语种 eng
中图分类化学动力学、催化作用;
关键词
Atmospheric chemistry; hydroxyl radical; butanone;

机译：大气化学;羟基自由基;丁酮;

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1. Direct kinetic study of the reaction of OH radicals with methyl-ethyl-ketone [J] . Emese Szabó, Gábor L. Zügner, István Szilágyi, Reaction Kinetics and Catalysis Letters . 2008,第2期

机译：OH自由基与甲基-乙基酮反应的直接动力学研究
2. Kinetic studies of reactions of the nitrate radical (NO3) with peroxy radicals (RO2): an indirect source of OH at night? [J] . Vaughan S, Canosa-Mas CE, Pfrang C, Physical chemistry chemical physics: PCCP . 2006,第32期

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DIRECT KINETIC STUDY OF THE REACTION OF OH RADICALS WITH METHYL-ETHYL-KETONE

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