Modelling of catalyst deactivation in liquid phase reactions: citral hydrogenation on Ru/Al_2O_3

Lasse-Pekka Tiainen; Paivi Maki-Arvela; Ahmad Kalantar Neyestanaki; Tapio Salmi; Dmitry Yu.Murzin

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Modelling of catalyst deactivation in liquid phase reactions: citral hydrogenation on Ru/Al_2O_3

机译：液相反应中催化剂失活的建模：Ru / Al_2O_3上的柠檬醛加氢

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摘要

Selective hydrogenation of citral was investigated at 70 deg C over Ru/Al_2O_3. Activity changes in a series of consecutive experiments were described by a mathematical model, which included reaction kinetics and deactivation.

机译：在70℃下在Ru / Al_2O_3上研究了柠檬醛的选择性氢化。通过数学模型描述了一系列连续实验中的活性变化，其中包括反应动力学和失活。

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《Reaction kinetics & catalysis letters 》 |2003年第2期| 共7页
作者
Lasse-Pekka Tiainen; Paivi Maki-Arvela; Ahmad Kalantar Neyestanaki; Tapio Salmi; Dmitry Yu.Murzin;
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正文语种 eng
中图分类化学动力学、催化作用 ;
关键词
citral; hydrogenation; deactivation; liquid-phase;

机译：柠檬酸加氢失活液相;

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1. Modelling of catalyst deactivation in liquid phase reactions: citral hydrogenation on Ru/Al_2O_3 [J] . Lasse-Pekka Tiainen, Paivi Maki-Arvela, Ahmad Kalantar Neyestanaki, Reaction kinetics & catalysis letters . 2003 ,第2期

机译：液相反应中催化剂失活的建模：Ru / Al_2O_3上的柠檬醛加氢
2. Inverse temperature dependence due to catalyst deactivation in liquid phase citral hydrogenation over Pt/Al_2O_3 [J] . Paivi Maki-Arvela, Narendra Kumar, Kari Eranen Chemical engineering journal . 2006 ,第3期

机译：在Pt / Al_2O_3上液相柠檬酸加氢中催化剂失活导致的逆温度依赖性
3. Thiophene as Internal Promoter of Selectivity for the Liquid Phase Hydrogenation of Citral Over Ru/KL Catalysts [J] . J. Alvarez-Rodriguez, A. Guerrero-Ruiz, A. Arcoya Catalysis Letters . 2009 ,第3a4期

机译：噻吩作为Ru / KL催化剂上柠檬醛液相加氢选择性的内部促进剂
4. Liquid phase selective hydrogenation of citral over Ru/Tio2 and Pt/Tio2 nano catalysts [C] . Ananthan S.A., Narayanan V. Nanoscience, Engineering and Technology (ICONSET), 2011 International Conference on . 2011

机译：Ru / Tio 2 和Pt / Tio 2 纳米催化剂对柠檬醛的液相选择性加氢
5. Ruthenium-based model catalysts for the liquid phase hydrogenation of bio-based organic acids and aldehydes [D] . Ma, Xianfeng 2013

机译：用于有机基有机酸和醛液相加氢的钌基模型催化剂
6. Alkaline ionic liquids applied in supported ionic liquid catalyst for selective hydrogenation of citral to citronellal [O] . Eero Salminen, Pasi Virtanen, Jyri-Pekka Mikkola 2014

机译：碱性离子液体在负载型离子液体催化剂中的应用用于将柠檬醛选择性氢化为香茅醛
7. Liquid phase hydrogenation of citral on zeolite supported monometallic (Ni,Pt) and bimetallic (ni-Sn, Pt-Sn) catalysts [O] . Güleç Hilal 2005

机译：沸石负载的单金属（Ni，Pt）和双金属（ni-Sn，Pt-Sn）催化剂上柠檬醛的液相加氢

Modelling of catalyst deactivation in liquid phase reactions: citral hydrogenation on Ru/Al_2O_3

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