Thermodynamic and transport properties for binary and ternary mixtures of 2-methyltetrahydrofuran + chlorobenzene + cyclopentanone at T = 298.15 K

摘要

Experimental densities p, viscosities η, and refractive indices n_D of the ternary mixtures consisting of 2-methyltetrahydorfuran + chlorobenzene + cyclopenta-none and constituted binary mixtures were measured at T= 298.15 K for the liquid region and at ambient pressure for the whole composition range. Excess molar volumes V_m~E deviations in the viscosity Δη, and deviations in the refractive index Δn_D from the mole fraction average for the mixlures were derived from the experimental data. The excess partial molar volumes V_(m,i)~E, were also calculated. The binary and ternary data of V_m~E, Δη, and Δn_D were correlated as a function of the mole fraction by using the Redlich-Kister and the Cibulka equations, respectively. McAllis-ter's three-body interaction model is used for correlating the kinematic viscosity of binary mixtures with the mole fraction.