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Synthesis and Characterization of a Phthalocyanine-Porphyrazine Hybrid and its Palladium(II) Complex

机译:酞菁-卟啉杂化物及其钯(II)配合物的合成与表征

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摘要

A phthalocyanine-porphyrazine hydrid molecule composed of three phthalonitrile units and one maleonitrile moiety was prepared by ccylomerization of the reactants n the presence of magnesium utoxide. Two thioether groups fused to #beta#-pyrrol positions were complexed with PdCl_2. The compounds were characterized by ~(1)H NMR, IR, and UV/Vis spectroscopy as well as elemental analysis
机译:在三氧化二镁存在下,通过将反应物进行三聚反应,制备了由三个邻苯二甲腈单元和一个顺丁烯二腈部分组成的酞菁-卟啉嗪氢化物分子。将两个与#beta#-吡咯位置融合的硫醚基团与PdCl_2络合。通过〜(1)H NMR,IR和UV / Vis光谱以及元素分析对化合物进行表征

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