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Molecular reorientation of a nematic liquidcrystal by thermal expansion

机译:通过热膨胀使向列型液晶分子取向

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A unique feature of nematic liquid crystals is orientational order of molecules that can becontrolled by electromagnetic fields, surface modifications and pressure gradients. Here wedemonstrate a new effect in which the orientation of nematic liquid crystal molecules is alteredby thermal expansion. Thermal expansion (or contraction) causes the nematic liquid crystal toflow; the flow imposes a realigning torque on the nematic liquid crystal molecules and the opticaxis. The optical and mechanical responses activated by a simple temperature change can beused in sensing, photonics, microfluidic, optofluidic and lab-on-a-chip applications as theydo not require externally imposed gradients of temperature, pressure, surface realignment,nor electromagnetic fields. The effect has important ramifications for the current search ofthe biaxial nematic phase as the optical features of thermally induced structural changesin the uniaxial nematic liquid crystal mimic the features expected of the biaxial nematicliquid crystal.
机译:向列型液晶的独特特征是分子的取向顺序,可以通过电磁场,表面改性和压力梯度来控制。这里展示了一种新的效果,其中向列液晶分子的取向通过热膨胀而改变。热膨胀(或收缩)导致向列型液晶流动;该流动在向列液晶分子和光轴上施加了重新排列的扭矩。由简单的温度变化激活的光学和机械响应可用于传感,光子学,微流体,光流体和芯片实验室应用,因为它们不需要外部施加温度,压力,表面重新排列或电磁场的梯度。由于单轴向列液晶中的热诱导结构变化的光学特征模仿了双轴向列液晶的预期特征,因此该效果对于当前寻找双轴向列相具有重要的意义。

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