Modification of mesoporous TiO_2 electrodes by surface treatment with titanium(IV) indium(III) and zirconium(IV) oxide precursors

摘要

Post-treatment of titanium dioxide (TiO_2) films for use in dye-sensitized solar cells has been carried out with titanium(IV), indium(III) and zirconium(IV) oxide precursor solutions. The nanostructured electrodes were characterized using nitrogen gas sorption (NGS), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), energy dispersive x-ray spectroscopy (EDX), field emission scanning electron microscopy (FEGSEM) and high resolution transmission electron microscopy (HRTEM). The change in the nanostructure was quantified and the thicknesses of the core-shell coatings determined. An evaluation of the dependence of thickness by HRTEM concluded that one coating step of either the indium or zirconium precursor gave thicknesses of 0.5 nm, with EDX and XPS confirming the presence of either In or Zr at the TiO_2 electrode surface, respectively. These working electrodes were then used to fabricate dye-sensitized nanocrystalline solar cells (DSSCs) whose performance was tested under AM1.5G 100 mW cm~(-2) illumination. TiCl_4 post-treatment was found to improve the photovoltaic efficiencies from 3.6 percent to 5.3 percent. Single coatings of either In_2O_3 or ZrO_2 on the TiO_2 working electrode resulted in an increased efficiency from 3.6 percent up to 5.0 percent. Thinner coatings gave the highest solar cell efficiency. The drop in performance was mainly due to a decrease in short circuit current density (J_(sc)) with the greater shell thicknesses. ZrO_2-coated TiO_2 electrodes subjected to microwave heat treatment using a 2.45 GHz microwave produced the highest efficiencies (5.6 percent) largely due to an increase in short circuit current from 11.4 to 13.3 mA cm~(-2).