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Tribocorrosion behaviour of nanostructured titanium substrates processed by high-pressure torsion

机译:高压扭力处理的纳米钛结构基底的摩擦腐蚀行为

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摘要

Aseptic loosening induced by wear particles from artificial bearing materials is one of the main causes of malfunctioning in total hip replacements. With the increase in young and active patients, complications in revision surgeries and immense health care costs, there is considerable interest in wear-resistant materials that can endure longer in the harsh and corrosive body environment. Here, the tribological behaviour of nanostructured titanium substrates processed by high-pressure torsion (HPT) is investigated and compared with the coarse-grained samples. The high resolution transmission electron microscopy reveals that a nanostructured sample has a grain size of 5-10 nm compared to that of ~10 μm and ~50 μm for untreated and annealed substrates, respectively. Dry and wet wear tests were performed using a linear reciprocating ball-on-flat tribometer. Nanostructured samples show the best dry wear resistance and the lowest wear rate in the electrolyte. There was significantly lower plastic deformation and no change in preferred orientation of nanostructured samples attributable to the wear process. Electrochemical impedance spectroscopy (EIS) shows lower corrosion resistance for nanostructured samples. However, under the action of both wear and corrosion the nanostructured samples show superior performance and that makes them an attractive candidate for applications in which wear and corrosion act simultaneously. (Some figures in this article are in colour only in the electronic version)
机译:由人工轴承材料产生的磨损颗粒引起的无菌松动是整个髋关节置换术故障的主要原因之一。随着年轻和活跃患者的增加,翻修手术中的并发症以及巨大的医疗费用,人们对耐磨材料产生了浓厚的兴趣,这种材料可以在恶劣和腐蚀性的身体环境中持续更长的时间。在这里,研究了高压扭力(HPT)处理的纳米结构钛基底的摩擦学行为,并将其与粗颗粒样品进行了比较。高分辨率透射电子显微镜显示,纳米结构样品的晶粒尺寸为5-10 nm,相比之下,未经处理和退火的基板的晶粒尺寸分别为〜10μm和〜50μm。使用线性往复式平面球式摩擦计进行干磨和湿磨测试。纳米结构样品在电解质中显示出最佳的耐干磨损性和最低的磨损率。塑性变形显着降低,并且纳米结构样品的优先取向没有因磨损过程而发生变化。电化学阻抗谱(EIS)对纳米结构样品显示出较低的耐腐蚀性。然而,在磨损和腐蚀的共同作用下,纳米结构样品表现出优异的性能,这使其成为磨损和腐蚀同时起作用的应用的有吸引力的候选者。 (本文中的某些数字仅在电子版本中为彩色)

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