...
首页> 外文期刊>Nanotechnology >Electronic and optical properties of finite carbon nanotubes in an electric field
【24h】

Electronic and optical properties of finite carbon nanotubes in an electric field

机译:电场中有限碳纳米管的电子和光学性质

获取原文
获取原文并翻译 | 示例

摘要

The effects, caused by the geometric structure and an electric field (E), on the electronic and optical properties of quasi-zero-dimensional finite carbon nanotubes are explored by employing the tight-binding model coupled with curvature effects. Electronic properties (state energies, symmetry of electronic states, energy spacing and state degeneracy) are significantly affected by the magnitude and the direction of the electric field and the geometric structure (radius, length and chirality). The electric field, by lowering the symmetry of finite carbon nanotubes, modifies the electronic properties. Thus, the optical excitation spectra, excited by electric polarization parallel to the nanotube axis, exhibit rich delta-function-like peaks, which reveal the characteristics of the electronic properties. Therefore it follows that geometric structure and E influence the low-energy absorption spectra, i.e. the change of frequency of the first peak, the alternation of the peak height and the production of the new peaks. There are more absorption peaks when E is oriented closer to the cross-section plane. Moreover, the very complicated optical absorption spectra are characteristic for the individual chiral carbon nanotube due to its specific geometric structure. Above all, the predicted absorption spectra and the associated electronic properties could be verified by optical measurements.
机译:通过结合曲率效应的紧密结合模型,探索了由几何结构和电场(E)引起的对准零维有限碳纳米管的电子和光学性质的影响。电子性质(状态能量,电子状态的对称性,能量间隔和状态简并性)受电场的大小和方向以及几何结构(半径,长度和手性)的影响很大。通过降低有限的碳纳米管的对称性,电场改变了电子性能。因此,由平行于纳米管轴的电极化激发的光激发光谱显示出丰富的类似于δ函数的峰,这揭示了电子性质的特征。因此,随之而来的是几何结构和E影响低能量吸收谱,即第一个峰的频率变化,峰高的交替和新峰的产生。当E的方向更靠近横截面时,会有更多的吸收峰。而且,由于手性碳纳米管的特定几何结构,其非常复杂的光吸收光谱是其特征。最重要的是,可以通过光学测量来验证预测的吸收光谱和相关的电子性质。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号