A novel surfactant 2-amino-6-decanamidohexanoic acid: Flotation performance and adsorption mechanism to diaspore

摘要

In this paper, a novel surfactant, 2-amino-6-decanamidohexanoic acid (AHA-10) was synthesized and used as a collector for flotation separation of diaspore and aluminosilicate minerals. The adsorption mechanism of AHA-10 onto diaspore was also evaluated by FTIR spectra, zeta potential, XPS and solution chemistry. The flotation results demonstrated that AHA-10 exhibited superior collecting power to diaspore and good selectivity against kaolinite and illite, and could effectively recover diaspore from bauxite ores contained aluminosilicate minerals at pH around 10. The analyses of FTIR spectra, zeta potential and solution chemistry inferred that at pH around 10, AHA-10 might chemisorb on diaspore surfaces by formation of Al-O and Al-N bonds. AHA-10's unique properties, such as characteristic bond model to Al atoms on diaspore surfaces, double hydrophobic groups and intermolecular hydrogen bonds between neighboring AHA-10 molecules coated on diaspore surfaces, rendering a weakening surface energy and enhancing hydrophobicity of diaspore particles. (C) 2016 Elsevier Ltd. All rights reserved.