Contact angle and bubble attachment studies in the flotation of trona and other soluble carbonate salts

摘要

Trona, Na_2CO_3 . NaHCO_3 . 2H_2O, is mined as the primary source for sodium carbonate production in the United States. Recent studies have shown that the flotation method can be used for pre-processing of trona ore to remove insoluble mineral contaminants for the production of soda ash (sodium carbonate). Studies with carbonate salts suggest that certain important factors can affect their flotation response, including viscosity of the brine and interfacial water structure. Flotation studies showed that contrary to the strong flotation of NaHCO_3 with both anionic and cationic collectors, Na_2CO_3 does not float at all. Based on the analysis of interfacial water structure in saturated brines, Na_2CO_3 was found to act as a strong water structure maker, whereas NaHCO_3 acts as a weak water structure maker. Bubble attachment time measurements suggest that collector adsorption at the surface of NaHCO_3 induces flotation; this is not the case for Na_2CO_3. Contact angle measurements indicated that the surface of Na_2CO_3 is hydrated to a great extent, whereas the NaHCO_3 salt surface is less hydrated. These results reveal that there is a strong relationship between the interfacial water structure and the contact angle of these salts. The less stable NaHCO_3 surface is ascribed to the interfacial water structure which allows for NaHCO_3 flotation with both anionic and cationic collectors.