Anodic passivity of some titanium base alloys in aggressive environments

摘要

The passivity of titanium, binary Ti- 15Mo and ternary Ti- 15Mo-5Al alloys in hydrochloric acid solutions was studied by potentlostatic, potentiodynamic, linear polarization and electrochemical impedance spectroscopy (EIS) techniques. The anodic passivity of binary Ti-15Mo and ternary Ti-15Mo-5Al titanium alloys differs from that of the base metal in hydrochloric acid solutions. The corrosion potentials of both alloys are nobler than of the titanium because the beneficial effect of molybdenum. The critical passivation current density for binary Ti-15Mo alloy is higher than of titanium; this fact can be explained by the instability of the constituent phases in hydrochloric acid solutions. Ternary Ti-15Mo-5Al alloy exhibits two critical passivation current densities (i{sub}(cr1) and i{sub}(cr2)) with higher values than of the base metal and two critical passivation potentials (E{sub}(cr1) and E{sub}(cr2)); at the first critical passivation potential (E{sub}(cr1)) the porous titanium trioxide (Ti{sub}3O{sub}5) is formed and at the second critical passivation potential (E{sub}(cr2)) this oxide is converted to a still higher valence oxide, the compact and protective titanium dioxide (TiO{sub}2). The dissolution current densities in the passive range of alloys are higher than of the base metal due the dissolution of the alloying elements in this potential range. The alloys are more resistant than titanium presenting lower corrosion rates. A three time constants equivalent circuit was fitted: one time constant is for the double layer capacity (C{sub}(dl)) and for the passive film (R{sub}p)); another time constant is for the charge transfer reactions visualised by a constant phase element (CPE) and a resistance (R{sub}1); the third time constant is for diffusion processes through the passive film represented by a resistance (R{sub}2) and a Warburg element (W).