Platinum fulleride reduction by molecular deuterium or 9,10-dihydroanthracene

摘要

C60Pt reacts with D-2 (1-2 MPa D-2 pressure and 373-723 K) to form C60Dx (X = 2-26) and Pt clusters. C-60 in platinum fulleride is also reduced by dihydroanthracene to hydrofullerenes. The value of E-b Pt4f(7/2) (72.4 eV) obtained for platinum in the starting C60Pt suggests partial charge transfer from the Pt atom to C-60 in C60Pt. [References: 11]