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Studies on the effect of antioxidants on the long-term storage and oxidation stability of Pongamia pinnata (L) Pierre biodiesel

机译:抗氧化剂对Pongamia pinnata(L)皮埃尔生物柴油的长期储存和氧化稳定性的影响研究

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摘要

This study investigates the impact of various synthetic phenolic antioxidants on the oxidation stability and storage stability of Pongamia (karanja) biodiesel (PBD). The results of Rancimat experiments show that the induction point (IP) increased substantially on adding certain antioxidants to the Pongamia biodiesel. The study reveals pyrogallol (PY) to be the best antioxidant to show the best improvement in the oxidative stability of PBD, the induction time being enhanced to 34.35 h at a PY concentration of 3000 ppm at 110 °C. The storage stability studies were carried out according to the ASTM standard procedures 1) ASTM D4625 at 30 °C/50 weeks and 2) ASTM D4625 at 43 °C/12 weeks by adding different antioxidants like BHT, BHA, PY, GA and TBHQ. The effectiveness of these five antioxidants on PBD was examined at varying loading levels during the storage period.
机译:这项研究调查了各种合成酚类抗氧化剂对Pongamia(karanja)生物柴油(PBD)的氧化稳定性和储存稳定性的影响。 Rancimat实验的结果表明,在Pongamia生物柴油中添加某些抗氧化剂后,诱导点(IP)大大提高。研究表明,邻苯三酚(PY)是表现出对PBD氧化稳定性的最佳改善的最佳抗氧化剂,在110°C下,PY浓度为3000 ppm时,诱导时间增加到34.35 h。储存稳定性研究是根据ASTM标准程序进行的:1)在30°C / 50周的条件下ASTM D4625,以及2)在43°C / 12周的条件下,通过添加不同的抗氧化剂,如BHT,BHA,PY,GA和TBHQ,进行ASTM D4625 。在存储期间,在不同的负载水平下检查了这五种抗氧化剂对PBD的有效性。

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