Identification of cremains using X-ray diffraction spectroscopy and a comparison to trace element analysis.

摘要

The ability to distinguish human cremains from filler materials can be important in a variety of situations, the most notorious recent example being the Tri-State Crematorium incident. However, the majority of the papers in the recent literature present methods that rely on trace or minor element analysis, usually followed by a statistical or variable cluster analysis, to determine attribution. This approach is inherently risky, as there is significant natural variation in the trace and minor element body burdens within the human population and no real baseline for comparison. Bones and teeth are a form of calcium phosphate that is part of the mineral group apatite, often referred to as bioapatite. X-ray diffraction (XRD) spectroscopy is a technique that is used to identify minerals by their crystalline structures rather than their elemental composition. The members of the mineral group apatite have a highly flexible hexagonal (6/m) structure that is able to incorporate small amounts of a wide variety of elements. However, its structure, and therefore its X-ray diffraction pattern, is distinct from the crystalline structures of all of the commonly reported filler materials, most of which are composed of some combination of Portland cement, limestone aggregate and quartz sand. XRD has several advantages over other analytical techniques for the identification of cremains. It is non-destructive, requires relatively small amounts of material, is unaffected by the elemental variations found in bioapatite, and can be used to semi-quantify the components of a mixture, thus determining the relative level of contamination of a sample. This paper presents the results of X-ray diffraction spectroscopy analysis of human cremains and a variety of common filler materials.